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Another data point--on trip from Los Angeles to Houston last week. Filled up with 91 (my usual drink of choice) in Palm Desert, California. Smooth freeway driving till I get into Phoenix, where I hit traffic. It's blazing hot (111F indicated), and I have roughly a third of a tank of fuel. Coasting down to a traffic jam by PHX airport, I notice throttle is no longer responding. I had enough momentum to shift into N (engine stalled at this point, lost power steering), and pull onto the shoulder.
No smell of gasoline, or any abnormal noises. Gas cap opened without hissing or anything. Waited for about half hour before it would run again. My next planned stop was the Costco in Tempe for fuel, so I hit the road again, and the car stalls while I'm on the offramp, in the turn lane.... Sat with hazards on hoping not to get run into.
The first time I had this issue was wheeling in the mountains, after stopping to take some scenic photos, and that time I definitely smelled gas and heard gurgles. The second time was also while wheeling, idle coasting down a trail full of snow after a climb. Don't remember if the gas cap hissed or smelled.
This time was the third confirmed time, but no smell or pressure release at gas cap. Also had my wife with me, who was ready to put her foot down and turn us around. Sitting on the side of the freeway in late afternoon heat was not fun.
After that, every time we stopped for fuel, I let the car sit with cap open while we took a break. My brother (same car) suggested I drive with the cap not tightened all the way, so I did. Don't know if that helped or not, but no further issues. No CEL or pending codes either (in the past I got misfires and catalyst efficiency low, from crank and hold, and trying to run the engine with throttle).
The gas cap gasket was changed about 109k, car is currently at 206k. I'm concerned about the return drive, especially during the hot and high portions of NM and AZ, and dreading the city traffic that is PHX.
PSKHAAT says it's made worse by higher octane fuel, which is interesting observation, so I may run the lowest available octane for the trip (not towing, stock everything, and drive like a grandpa I'm told).
Definitely when I get back, going to have some heat shielding put in between the cat and the fuel line, and if possible some insulation around the gas line as well. It was the plan this summer, but had something come up where I had to drive to Houston on short notice.
one last note, your driving a 2006 and I I don't know if Lexus, the same as Toyota, switch toVVTI motors in 2006. If they did, you're going to want to upgrade your fuel pump. You may have an earlier 2006 fuel pump which is not the upgraded model. There is a factory upgrade and if you replace your fuel pump, I don't believe you can get the older fuel pump. Private message me if you have any other questions good luck on your trip.