I live in the ATX, do all my AC work, and take cool air seriously. An often overlooked part of this deal is a fully functioning cooling system. If you're not drawing hot air off the radiator, either through airflow from driving or from a good fan and shroud combo, you'll get heat soak in those parts (where your condenser is), and the temperature will go up. If you live somewhere genuinely hot, (*edit-I just looked and saw you're in CO, the thin air there makes it harder to pull heat out, so the fan would help you there too.) you might consider one of the many condenser fan kits the vendors sell. They make a big difference at low speed, and at idle.
To answer your question, though, on a 98-100-degree day here, with average to high Texas humidity, I get 39-40 at the vent going down the road and 41-43 at idle.
I agree about checking the heater control valve, but I've never personally seen one malfunction. I'm not saying it doesn't happen, and it's an easy check. Also, DEFINITELY clean out the cooling unit box. If you've never done it, it will be full of crap that will restrict the airflow. It's not quite as easy, but it's much more likely to be a problem. If your temperature goes way up after driving, your expansion valve could be the issue.
In any case, all of this is available, OEM stuff can be picked up at RockAuto and you can redo the whole system for a few hundred dollars (minus the compressor, which really never fails unless you run dirty refrigerant or the wrong type or level of oil through it) and you'll have the aforementioned "Anniston Temps".