You had me pretty frazzled because I thought you were going to try to use a 2-pin alternator, which are externally regulated by the PCM to provide appropriate voltages for the Chevy body electrics. Everything I've read says to avoid the 2-pin alternators and use the 4-pin which are internally regulated.
You should be good to go.
Now you just need to go buy a 145-amp alternator and it will bolt in to your set up.

Look for one with the black ring between the two case halves. I just posted a picture in my thread of my 145 amp alternator, I won't clog your thread up with my pictures.