My 72 is round at the heater/defrost junctions. From the blower motor to the heater is a rectangular duct. I used glue and a industrial stapler to make the rectangular duct from a piece of car innertube back in like 84 - still there, still works. I bought new defrost ducts about that time. The hoses still appear good but the fittings are rotten. I thought about 3d printing new ones, but PVC could work nicely.
You can form PVC with a heat gun. Measure the oval circumference, match that to a round section fitting. Heat the fitting and then press it in place quickly using a glove. It should be easier to stretch a slightly smaller fitting to fit than to collapse an over sized one. Silicon calking is an option too.