That's fine if both batteries are in working order, but in the event of a battery failure, you want a proper connection between both batteries that can handle a large draw
If your isolator is only rated for 150-200 amps and you're trying to pull a 450amp load through it, things will get ugly
Ive got to disagree with you again (sorry).
If your winch is drawing 450 amps (about max load) then you should be drawing aproximately 225 per battery. Which shouldnt kill an isolator for short durations.
Just about every diesel pickup on the road runs two batteries with out isolators, and they dont seem to worry about battery failure. Split whatever load your putting on them in half, instead of running all the load on one in case it blows up. I just cant wrap my head around having a spare when you could share the load between them. They are stronger together then individually, and should fatigue less sharing the load.
If your worried about your truck die'n and not being able to start, then:
A. you should be wheeling in groups of people anyways. If you want to jump yourself, youd actually be better disconnecting the battery thats dead instead of jumping it, and using the good battery to start the vehicle then let the alt recharge it, not let the good battery run current to a dead one and start the truck.
B. but a low charge cut-off relay on your fridge or lights or whatever loads you have.
C. install a cut off switch near your dash (you know the kind with the removable red handle) that cuts power to everything but: your starter, your winch and your clock/radio. Have it re-route and kill power to your fuse panel and auxillary panel that supports your fridge/inverters etc.
This will also work as a theft prevention system, and will allow you to avoid any electrical drains should you decide you need to leave it sitting for weeks at a time.