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As Hornd said, if your able to smell coolant at the tail pipe, it's time to do a compression test to see if you've got a bad head gasket. Another test you can do, is the dye in your coolant system test. If the dye turns color then that means you've got exhaust gases leaking into your coolant system, and that too means it's time for a head gasket.Smell the tailpipe....No I'm serious.
All of the above however, a pressure test of the cooling system will not always show up a leaking head gasket, whereas the dye detection of gases in the coolant will almost certainly will. The reason is the gasket 'fire ring may be just 'letting by' with 250+ psi of pressure behind it but, the other direction from the cooling system is only around 20 psi and not make it across. Also might be worth checking your transmission dipstick if you have an auto, a high level there with the oil looking like a strawberry milkshake will mean the trans cooler in the bottom of the radiator has failed.
regards
Dave
And the dye test will not find all head gaskets leaks, none of them are 100% definitive.
The dye test is sort of negative confirmation - if it detects combustion gasses you have a bad headgasket. If it doesn't detect them, you still might have a bad headgasket.