80W90 is a conventional fluid and may or may not have a LS additive in it. Since it's conventional, it's probably already a GL-4. I'd personally run it and not worry about it - you just have a slightly thicker fluid than the 75W so you'll have minimally worse fuel economy.
I know this is not a transfer case, but below is a photo of my rear differential at 18 years and 190K miles. The last 5 years/50K of it's life it was lubricated with Valvoline 80W90 conventional, LSD-free GL-4 in it, changed yearly. This little 8" diff was used for towing our camper thousands of miles and several other trailers over 5,000 pounds, plus quite a bit of wheeling. I have no idea what the POs before more ran in it, but the diff had essentially zero wear.
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