LTO Starter Battery

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Did you adjust the alternator voltage up with caps or a resistor?
 
You may want to regulate the current somehow so you don't burn out your alternator. I was more concerned with the charge voltage profile being designed for LA. I know my vehicle alternator is temperature compensating, so it only puts out ~13.4V when warm and probably wouldn't play nicely with more exotic Li chemistries. I imagine the smart alternators would play even less nicely.
 
Did you adjust the alternator voltage up with caps or a resistor?

I didn't, as when it was running the SLA, it was charging at 14.5v, which is "ideal" for what I am running. It is interesting that the car now runs at a lower voltage (14.1-ish), so it is something I may consider. If it continues to charge at low 14s, I will def consider modding it to bring it up to 14.5

You may want to regulate the current somehow so you don't burn out your alternator. I was more concerned with the charge voltage profile being designed for LA. I know my vehicle alternator is temperature compensating, so it only puts out ~13.4V when warm and probably wouldn't play nicely with more exotic Li chemistries. I imagine the smart alternators would play even less nicely.

I have considered this. Short version: As they are 35AH cells, the time taken to charge them to 14.5 volts is fairly low. Even if I didn't drive it for a few days, there would be 0.1AH draw max, so a couple of AH. To recharge 2.5AH would take (at 25amps) 6 minutes. Even if the alt was cooking at 100amps, it would be less than 2 minutes. This is assuming it is putting out the max amps, which it wouldn't, as the voltage difference got smaller. I am pretty sure that a Ford escape 2010 doesn't have a smart alt, but I should double check anyway..... one should never assume!
 
I used a 1A diode. Don’t remember what voltage it was rated at. Got 0.5v increased charge with it In place
 
Charger: The BMS won't pull more than 80A, so I"m hoping not to have to get an external DC DC solution. Definitely a test and see situation. I do not need the pack to go to full V (2.8V/cell). Totally happy with it at the alternator max - let's call it 13.8 to 14v pack (2.3 v/cell). It won't change the LTO CCA output at this cell voltage, and simplifies system and cost. Will reduce capacity as a key off accessory system, but I'm okay with that.

Yes, the cell resistance is Low. I"ve found 800A fuses in ALN format. It's about $40 for the fuse and holder. The thing is, the stock starter battery isn't fused . . . I'm not sure why or why not, and hope to get a good discussion going on this point!!

LTO is -40C to +55C. Lead Acid is similar, rated to +60C. I'm not fussed over that +5C difference. The viability of lead acid in +55C if you look at a curve is near zero. That battery is never going to work again. LTO will at least recover.

LTO has a different set of drawbacks to LFP, mainly weight/size/density and cost. It seems to be superior in pretty much all the other measures.
ANL fuses while offering a very wide range of rated amperages, don't have great Interrupt Capacities. Class T offers IC of 20kA, Terminal Fuse (aka MRBF) 10kA, ANL 6kA and MIDI 5KA. I uses MRBF's on my system due to fairly high IC, useful rate of 30 to 300 amp sizes and compactness.
 
HIgh C-rates definitely allow for high current availability in a small capacity package. I can see the desire to use these as a starting battery, and for car manufacturers to eventually go in that direction.

Not as good though for low C-rate long duration draws I would think. That is where LA or LFP excels.
 
ANL fuses while offering a very wide range of rated amperages, don't have great Interrupt Capacities. Class T offers IC of 20kA, Terminal Fuse (aka MRBF) 10kA, ANL 6kA and MIDI 5KA. I uses MRBF's on my system due to fairly high IC, useful rate of 30 to 300 amp sizes and compactness.
*** edit *** didn't realize I was responding to year old stuff. Sorry.
 
HIgh C-rates definitely allow for high current availability in a small capacity package. I can see the desire to use these as a starting battery, and for car manufacturers to eventually go in that direction.

Not as good though for low C-rate long duration draws I would think. That is where LA or LFP excels.
I think the appeal is:
- extreme longevity and reliability
- extreme temp operational envelope
- very safe
- weight savings over SLA
 
*** edit *** didn't realize I was responding to year old stuff. Sorry.
Fully agree on using a class t fuse. I did get one for my LTO project, but when the cells went missing ended up using it instead as a fuse on my winch install:
 
I didn't, as when it was running the SLA, it was charging at 14.5v, which is "ideal" for what I am running. It is interesting that the car now runs at a lower voltage (14.1-ish), so it is something I may consider. If it continues to charge at low 14s, I will def consider modding it to bring it up to 14.5



I have considered this. Short version: As they are 35AH cells, the time taken to charge them to 14.5 volts is fairly low. Even if I didn't drive it for a few days, there would be 0.1AH draw max, so a couple of AH. To recharge 2.5AH would take (at 25amps) 6 minutes. Even if the alt was cooking at 100amps, it would be less than 2 minutes. This is assuming it is putting out the max amps, which it wouldn't, as the voltage difference got smaller. I am pretty sure that a Ford escape 2010 doesn't have a smart alt, but I should double check anyway..... one should never assume!
The potential trouble would be driving the alternator at full tilt for an extended period of time, maybe 30 min? I had decided to put a choke on the alternator Input by adding a small series resistance, of 1 ohm or thereabouts. Did some calcs and stainless steel m6 all thread would do it, need around 10cm of it. Could adjust the length to provide the target resistance. Only an idea, as I never built the battery.
 
The potential trouble would be driving the alternator at full tilt for an extended period of time, maybe 30 min? I had decided to put a choke on the alternator Input by adding a small series resistance, of 1 ohm or thereabouts. Did some calcs and stainless steel m6 all thread would do it, need around 10cm of it. Could adjust the length to provide the target resistance. Only an idea, as I never built the battery.
Agreed. There are RV and marine folks who have dealt with this for LFP batteries. Check diysolarforum.com
 
I appreciate the full tilt alternator advice. This will not be an issue. The car is driven daily, the battery is 35ah, the overnight draw did not show a drop in voltage, keeping in mind that these batteires don't lose charge while sitting, only to running my alarm... unlike SLA.

In the event that I add another battery, or go van-lyfe, I will sort it out.

Small update. It is the air con that is causing the voltage sag. When it is on, I get 13.8 - 14.0. When it was off this morning and it was cool(ish) 20C or so, it charged up to 14.3 within 30 seconds. (Which is another factor for me not to worry about the alt catching on fire :D )
 
Yes, I get that you’re not planning to use the battery for house duty. And agree that the only risk is if you drop it down to say, 5ah. Even so, 150/30 is 5, so you should get that 30a in 60/5, 12 min. Probably won’t cook the alt in 12 min. Put the resistor in line to drop the alt down to 120A effective, and it would take 120/30,4 60/4, 15 min to recharge and no worry of cooking the alt. Glad to see an LTO in use and very curious to see what else you learn from living with it for a bit.
 
Still running well. Next up is adding a balancer (Heltec), with a voltage sensitive switch, so it only balances over 13.8v
In another week or so I will pull it, do some voltage tests on each cell. Probably should lable the cells too :D

If everything goes to plan, I will make another, do a youtube video of the making of it, get it installed in the wife's car. Or something :D
 
Added a balancer as above, ordered 2 new boards as I broke the solder patches and had to "dodgy" the on switch... sigh.
Been going for 3 months or so, still planning on making another, I have the cells, just made the bus bars and will make some design improvements on this next one. The balancer uses SFA power. Once the new one is complete, I will drop that one in the car, take the old one out and capacity test it.
Then, assuming no issues with the "old" battery, I will improve the configuration and put it into the wife's car.
As a side note, Heltec have apparently made custom active balancers that have a voltage detection circuit for LIPO4, so they only run at the very top of the charge cycle.

While that would be cool for my application, it really doesn't make any difference.
 
I inadvertently stress tested it today. I had it out to find a fault (loose balancing wire) so I did a capacity test. It came back same capacity as when I put it in, which is even better than I thought it would be. Of course after the capacity test, you charge it back up and drop it in, right? Not so much.
I put it back in at 12v. Got in the car, saw it was super low and thought wth? Even with maybe 3-6ah left in it, the car started first pop. (2.5L NA) Drove it 2 minutes to the shops, during which time the voltage showed low 13s. At the shops on accessories only, it had been brought up to a bit over 13v. No problem restarting, 13.5v - 14v on the 2 minute drive home, sagged back on turnoff to 13.5v.

These are the times when watching the alt temp would be a good idea, especially here in QLD where it is 30C and I am running the aircon plus lights. Still, I am super impressed with the setup. Once I get proper lugs for the balancer wires, it will be all go! A Youtube vid will (probably) follow at some point, where I show making up the second battery, missing out all the mistakes I made with the first one!
 
Hi guys, I just registered because I found this thread on Google. I just wanted to let you know that I did the very same thing. My 6s LTO battery is running strong. Here is my thread:

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lto1.jpeg
 

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