OK, generic vs. name brand - neither will leach into the soil under normal conditions and use. Vinegar is an acid and can be used as an additive to acidify your solution. So can a product put out by miracle grow called mir - acid, it is used for azaleas and camellias out west and those areas that have highly calcareous soils. (high pH due to calcium and high salts and other problems).
A surfactant to put in lay mans terms, makes water "wetter", it reduces water tension. Ivory liquid soap will do the same thing in small amounts. A surface - active - agent ie: surfactant will spread the water droplet so that each droplet (of spray solution) covers more area.
Additionally it depends on what part of the country you live in. Hot dry climates will produce plants with a thick(er) waxy cuticle that helps the plant retain moisture during times of heavy transpiration. So living out in the west, with our water pH's in the 7+ range, and the types of adaptations the plants have developed, we will use an acid or buffering agent to lower the acidity to cut through the waxy cuticle.
So Canman, do you have access to a local Pest Control Advisor (PCA) or Certified Crop Consultant (CCC).
Additionally, you can contact a local Ag Chem company and speak to a sales man (who will have some kind of certification to work in his state)who can direct you to the proper usage based on your conditions in your area (which I think is in the NE).
PM me if you have any questions, I spent 20+ yrs in Ag and 13 as a PCA (in Calif) before I became an LEO.