Notice in this image that there are two ways to connect the multi-meter for two different types of tests.
In one configuration...the Ammeter...current generated by the Alternator for charging the battery is measured in Amperes (thus an Ammeter measures Amperes).
In this configuration the Multi-meter is set to measure Current (Amperes) and is connected in series with the wire that goes between the battery and terminal B on the Alternator.
...by removing that wire at terminal B on the Alternator, connecting the black(-) lead of the Ammeter to that recently removed end of the wire and the red(+) lead of the Ammeter to terminal B...
NOTE: in this configuration, you are measuring significant amounts of current (10 amps!!). Be very careful! Current (not voltage) kills. If you are going to take this measurement, make sure it is set up correctly following the FSM guidelines, that the connections are tight, and the multi-meter is correctly set to measure Current (Amperes). I would install the multi-meter with the engine off, and after having installed it correctly, start the engine....and when uninstalling the meter...first turn the engine off. Also, make sure that your multi-meter can handle that amount of amperes...
The second configuration is to set the multi-meter to measure volts. After reconnecting the wire from the battery to terminal B on the Alternator, ground the black(-) lead of the Voltmeter and connect the red(+) lead of the voltmeter to terminal B on the Alternator. Make sure the multimeter is set to measure volts.
If you aren't comfortable taking these measurements, call local Autoparts stores to see if they do free battery/alternator testing and ask if the battery/alternator must be installed on the vehicle or removed during testing...