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Octane number as a function of boiling range
The
octane number decreases in general with increasing boiling range
[1],
[2]. This. effect is, however, different for different types of fuel. It is more pronounced for straight-run gasoline
[2]. This is probably due to greater variation in the composition of straight-run gasolines as compared to
reformate or racked gasoline.
Increasing the mid-boiling point tends to decrease octane quality
[2],
[3]. Increasing the mid-boiling point from 40 °C to 180 °C is accompanied with a decrease in the
motor octane number. The magnitude of this decrease depends on the type of fuel. It ranges between 42 for straight-run gasoline to 6 for catalytically cracked gasoline
[2].
Effects of the initial boiling point (IBP) is significant because light compounds in gasoline (C4 hydrocarbons) have high blending octane values and increasing the IBP can substantially reduce octane quality.
Similar effects are observed if 90% boiling point or final boiling point is changed, because even though the higher boiling fraction of gasoline is relatively high in aromatic content the total gasoline fraction is low in octane due to the diluting effect of a high paraffin content. Hence, a reduction in the final boiling point can result in higher overall gasoline octane
[2].
Increasing the 90% boiling point seems to decrease the octane number in most cases with the exception of the catalytically-reformed
naphtha where a slight increase in the octane number is observed. The octane number of the catalytically-cracked naphtha on the other hand, is not greatly affected by the 90% boiling point. The different relative amounts of aromatics and paraffins in the naphtha fractions is the most likely explanation for this anomaly.
A close study of the relationship between the octane number and boiling range indicates that for higher octane numbers and lower boiling temperatures (50%, 90% etc.) the correlation tends to be more significant. The change in octane number ranges from 5 for gasolines of 40 °C mid boiling point to 41 for gasolines of 180 °C. Similarly the change in octane number ranges from 19 for gasolines of 140 °C (90% boiling point) to 41 for gasolines of 200 °C
[2],
[3].
Method of Study and Results
To ascertain the relationship and correlation between the
octane number and the boiling range, data were collected from the Octel Co.
[4] and the Horns Oil Refinery (HOR) in Syria (platforming unit) as well as from other sources including the Banias Oil Refinery in Syria. A total of 1142 value points were used in the analysis. Regression Analysis of these data (using the least squares method) was carried out using a specially-prepared computer program
[5],
[6]. The boiling points considered in this analysis were the 10%, 50% and 90% boiling points as measured by the test method ASTM D86 (measured to the nearest 1 °C). In each case correlation factors and average errors were computed for the best correlations.
These optimum correlations did not however lead to simple easy-to-apply equations. For this reason straight-line correlations assuming linear relationships were included for comparison purposes.
Three runs were tried for each boiling temperature. The octel data were used for the first run. Data from HOR-Platforming unit were tried next, and finally both Octel and HOR data as well as data from other sources were used. The results obtained are given in
Table 1,
Table 2,
Table 3.
Table 1. Optimum and straight-line correlation between
Research Octane Number and 10% boiling point