To free up a sticking door lock cylinder (the quick way) I've used CRC Electronics cleaner (tall red can); stick the red tube into the slot/key door and give it a couple of good squirts. That will blow through all the pins cleaning out the old hardened original lube or anything else that's been put in there. Hold a rag around the red tube to catch any backspray.
If you have OCD then remove the door panel, peel down the vapor barrier,
then spray the cleaner into the lock cylinder while holding a rag over the cylinder from the inside, work the key, etc, or remove the cylinder and then clean it.
Follow that up with a lock lube of your choice (I use Krytox but it's crazy expensive). Reason for using the Electronics cleaner (instead of Carb/Brake cleaner) is that it won't melt plastic or damage paint instantly like those others will.
Here's a link to a way too wordy thread about how to pull a door lock cylinder apart and cleaning it up. I had the door handle out already to fix a crack in the handle so went ahead and pulled the cylinder apart.
Personally I don't however recommend pulling a cylinder all the way apart just for cleaning as it is way to easy to lose the tiny springs for the pins. If you have the cylinder out of the door/handle and in your hand then just blasting it with
any solvent while inserting and turning the key then relubing will do the job IMO.
I pulled the DS door handle assembly out to repair a crack in the handle and to check the lock cylinder. I'd noticed that the lock was a bit sticky and notchy so figured I'd look into it. Once I had the cylinder housing in my hand I could see when I turned the key it took half a second to...
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FWIW