From SOR.com-
7/70 - 9/75 When pressing on the brake pedal a hissing sound, a rapid change in idle or a rough idle are signs of a brake booster malfunction. Bad boosters will burn the exhaust valves in #5 & #6 cylinders. To Check Your Booster: Engine Off - press the brake pedal several times, pedal travel should not change. Start engine, pedal should move down a little and the pedal pressure will get softer. Press the brake pedal all the way down, shut off the engine, the pedal should not change position. Restart the engine, run for a minute and shut off, press the pedal several times, the pedal pressure should get harder each time. If your booster does not work this way its time to rebuild or replace it. Before buying the repair kit please refer to the factory Chassis/Body manual for the repair procedure.
BTW I'm convinced its either the booster is bad, or a vacuum leak at block. Thats the only part of the brake system that makes a hiss. Replace your intake/exhaust gasket with two stock ones from SOR and the hose from intake manifold to booster before you assume the booster is bad, I did those two things and now I no longer have a hiss.