Pull the line to the charcoal canister and cap where it came from and see what happens (cap at carb spacer from your description). If your charcoal canister isn’t functioning properly it’s going to hinder tuning.
Where’s the PCV hooked to?
Did you try sucking on the line to the distributor and see if it held? If it doesn’t hold then the diaphragm is bad and is a vacuum leak source.
You should be able to run the mixture screw (on valve cover side of carb) about 2 turns out from lightly seated, then fine tune from there for vacuum. If you set it there and it won’t idle, then it’s the dance of timing and curb idle adjustment (the screw you are pointing to), provided you’ve found no vacuum leaks.
You can also cap every vacuum port you have, brakes and all, then get the carb and timing dialed in. After that, start adding 1 vacuum “accessory” at a time and readjust. I’d start with brake booster, which should require no adjustments unless the booster diaphragm is leaking, in which case it needs replaced.
Next I’d add PCV and you will need to slightly adjust because it’s an intended vacuum leak essentially.
Then charcoal canister if you’ve determined it’s good and properly functioning. (It most likely isn’t).
Then vacuum advance after you’ve determined that diaphragm isn’t leaking, but no readjusting for vac advance.
Wow, that got long. Others may do this differently but this way isolates each potential leak as you go.