Some 2016+ had issues with the air metering doors in the dash doing odd things, that would be my focus. You can initialize them with techstream to see if that gets them working.
Modern cooling systems are really good about keeping air out of the parts it shouldn’t be in, as long as the level is high enough. At L or even a bit below it should be plenty, I don’t see any reason to burp the system.
If you want a little confirmation open the hood and check whether the heater lines on the passenger side of the engine bay get hot as the engine warms up from cold. They should get warm water pretty quickly, probably even before you’d feel the radiator warming up, as the system is set up to prioritize the heater cores for passenger comfort in cold weather.
If those lines get hot you have plenty of hot water, the issue is the doors in the dash not actually allowing air through the core. My gut is that’s the issue here, or maybe a vent temp sensor going bad.
What is your rear heater doing? Make sure it is turned on, set the temp back there to all the way hot, and see what happens.