as mentioned elsewhere, don't hook up panels of different voltage in parallel without looking deeper into it, it's generally not a good idea.
Alligator clips are also usually not a good idea outside of quick tests, IMO.
Keep in mind that you can in principle use more than one set of [panel+controller] at the same time to charge one battery. However, if one is PWM, it could conceivably do something weird to the other one, depending on the design, but it's a long shot, I think. And if the other one is a Victron, it can likely handle it, anyway. I would not hesitate much to do it, personally. In fact, I probably have done that before, and since I don't remember, there likely was no explosion...
added: FWIW, in case you were contemplating that, it's best not to use a PWM controller on a panel that has a significantly higher nominal voltage than the battery you want to charge, like your 38V panel with a 12V battery, say, because the panel will operate way off the MPP and you will lose a lot of power.