There are tons of good threads on LFP at diysolarforum.com. There's a whole thread on why you shouldn't charge below 0F.
Why you cannot charge LiFePO4 below 0 degrees Celsius - https://diysolarforum.com/threads/why-you-cannot-charge-lifepo4-below-0-degrees-celsius.2912/. That's not to say you can't do it, just that it will permanently harm the battery. (Note that it's cell temp, not ambient temp, so it's possible your cells can be a bit warmer than the air temp and still be "above 0C"
Now if your battery has a BMS (and many do have a cheap internal one) it should prevent you from doing really bad things like discharging or charging outside the cell temp range or over/under charging the cell voltages.
The Valence specs clearly state charging temp is 0C to 45 C and discharge is -10C to 50C. The chemistry of LFP batteries is all essentially the same. LFP is LFP is LFP. If you're using it to start when it's 0F out you're harming the battery. On top of that if you're not charging at 14V+ then you're never getting a full charge.
I don't know why you'd pay 3-4x the cost for a LFP battery to then abuse it and end up with a battery life that is equal to or less than a cheap FLA but do whatever you want I suppose.
Specs from
Valence U27-12XP Lithium Ion Battery Module | Greentec Auto - https://www.greentecauto.com/hybrid-battery/repurposed-batteries/valence
Voltage (nominal) 12.8 V
Capacity @ C/5, 25 °C (typical) 138 Ah (New)
Energy 1.76 kWh (New)
Discharge Cont./Peak (30 sec) 150 A / 300 A
Discharge Cutoff Voltage 10 V
Recommended Charge Voltage 14.6 V
Charge Float Voltage Range 13.8 - 14.6 V
Recommended Charge CCCV ≤ 72 A to 14.6 V
Discharge Temperature -10 °C to 50 °C
Charge Temperature 0 °C to 45 °C
Self Discharge @ 25 °C < 2% per month
Terminal Hardware M8 x 1.25
Terminal Torque 25 Nm 222 in-lbs
Plastic Case Flame Retardant
IP Rating IP56
Features
• >4000 cycles at 80% DOD
• Create systems 12 - 1000 V
• Series and/or parallel operation
• Automatic cell monitoring & balancing
• Temperature monitoring of cells
• Rugged mechanical design
• Thread locking feature
• Footprint of Group 27 lead acid case
• Maintenance-free
• No hydrogen generation or gassing
Height: (excluding bolts) 225 mm 8.86”
Width: 172 mm 6.77”
Length: 306 mm 12.0”
Weight: 19.2 ± 0.1 kg 42.2 lbs
Cell Configuration: 4IFpR27/66-44