You might want to keep a notebook handy with Toyota TechStream on it.
- You can hopefully check sensors: 02, Mass Airflow, etc.
- I'm not sure if this provides fuel rail pressure
Start with the basics: Air, Fuel, Spark
- I presume you have air
- Plug off a plug wire, verify you have spark during the failure
- Crank the engine a few times and then pull a spark plug. Is it wet? Got fuel?
- If it is wet and you have spark, then your mixture is off and that puts you on a sensor hunt.
I also really like the website
www.justanswer.com. For $15 to $20 you get access to a Toyota technician. They will walk you through the troubleshooting process. I have no affiliation with this website. I have been very pleased with the expertise I have received on 2 really bizarre problems on an Avalon. They are much better than my local stealership.
Good Luck.