Large crescent wrench (~2" jaw capacity IIRC), approach from the right side of the vehicle, won't be able to swing it in a complete arc due to the hood but it should get it started. If needed strike the handle of the wrench with a deadblow hammer or similar to break the nut free.
Already mentioned heat (Propane or MAPP gas torch kit, Home Depot), then penetrating oil, repeat. Be very careful where you point the torch, best if you use a welding blanket or similar to protect wiring, rubber, plastics.
There's a bunch of other things that can be worked on while you're in there:
Replace Heat control valve
Replace all heater hoses and PHH (USE OEM or Gates GreenStripe hose)
Replace Valve cover gasket
Replace Valve cover spark plug tube seals
Reseal half moons front of head
Clean Throttle Body completely including all small vacuum ports
Clean EGR valve once it's off
Clean the EGR gas tunnel inside the upper intake plenum (clean the whole thing)
Rewrap engine harness especially near EGR pipe, add heat insulation sleeve
Consider sending injectors off to be cleaned while the intake is off
Tip: be very careful working around the sensors on the left side of the engine (very easy to break the old plastic if bumped)