I believe Discoveries come from the factory with gear oil and not grease in their CV joints. A mixture of grease and gear oil can be added if so desired by the owner.
Anyway, swapping out the lubricant in a Disco involves simply draining the old, and filling with new. Depending on the job, the knuckle may be dissasembled to replace seals, especially knuckle wipers which obviously develop quite a leak with this setup. I know, big surprise, a Land Rover with a leak.
Aside from that (to add some 80's content to this thread), the Disco's birfield is the same size as earlier Land Cruisers (40, 55, 60 series), where as the 80 series is about 1.5 times as big.
And just some more information, so that I can flex my noodle, Series II Discoveries (1999 - 2004) dispensed with the enclosed birfield style joint and intead use one protected by a rubber boot, similar to what you'd see in an IFS vehicle.