The video offers interesting effects of different octane fuels and different types of fuels on the same engine. A compression test wont 100% accurately verify your compression ratio, but it might get you an idea. It may give you a good guess using the atmospheric pressure on the given day you do the test. Imo, with your timing set at 36* and your using a higher octane fuel to compensate for pinging tells me your timing is probably too far advanced. Running a higher octane isn't going to hurt anything, but pinging will.