It "should be" a simple matter to do that. Pin 30 is the power source for your aux lights...so if you're running 24V bulbs then you hook Pin 30 to the 24V post. If you're running 12V lights (not recommended as it takes power from your converter), then you hook up Pin 30 to a 12V source.
Pins 85 and 86 power the coil that throws the switch in the relay. If you don't have a relay that has a diode inline with the coil, then it doesn't matter which pin you make ground and which one you make positive. Let's say you have a standard relay with a resistor inline with the coil. Let's arbitrarily make Pin 85 ground, and Pin 86 positive. You will hook up Pin 86 to the 24V terminal of your battery (or a switched source if you want that), then to a ON/OFF swtich that you will use to manually control your lights, then to the relay. In order to automatically turn on the aux lights with your high beams, find the wire in your headlight wire harness that is energized with +24V when the high beams are on. The tap into this wire and connect it
between the ON/OFF switch and the relay. This way the relay will see +24V and flip the lights on with your high beams no matter what your switch is doing. You will also have to properly put in a
diode inline with the wire that you've attached between your high beams wire and the relay...or else your high beams will flash on when you flip your switch to turn on the aux lights.
Pin 87a is a normally closed connection with Pin 30...so you will not use this Pin.
Pin 87 is the normally open connection with Pin 30, and this is where the (+) wire of your aux lights should be connected to.
The only tricky part of this circuit will be finding the right diode and connecting it properly in order to prevent the relay circuit from turning on your high beams when you turn on your aux lights. Other than that, it should be fairly straight forward...I think.

Anyone else spot a flaw in this quickly thought-up plan?