Don't take this for Gospel, but I am pretty sure this would work. What I am thinking that if you set it up like this you could still charge both batteries with the standard 12 volt alternator and have a constant 24 volts available on the other circuit.
It would require either using marine batteries, (have been using one on my 4runner so that my 12V winch has its own terminals) or a regular car dual post battery like either the 78DT or a 34DT.
hope this helps.
The more I look at it the less I am sure though, might want to run this by a friends before trying it but I feel good enough to at least try it on my truck. if I was trying to get 24 volts, which I am not. I wish we had soem spares out here I would go wire it up on the deck to check it out with a volt meter for yah before you went and spent the money on it.
Seems like alot of trouble, just how cheep is the 18,000 and how bad are you planning on getting stuck?