Try some searching for head gasket replacement and read through a few of those threads.
There a a few dozen possible things that could be serviced, cleaned, painted, wrapped, repaired, or replaced while the head is off.
@Lknmud : it's a very long list, here's some:
Rebuild head (machine shop) with new valve stem seals. Consider new springs or valves as needed). Might be better off buying a new head
Replace oil pump cover gasket/O-ring and front crank seal if not done yet.
Replace water pump
Replace Thermostat
Replace Heat Control Valve
Replace all heater circuit water hoses including the PHH, bypass hoses, radiator hoses, and paint/replace pipes
Replace fuel filter
Replace all vacuum hoses on the Throttle Body and located under side of intake plenum. Test both VSV's for proper function. You can buy the correct Toyota bulk 3.5mm vacuum hose and cut to fit.
Replace fuel rated hose at top of Throttle body, you will have to cut it off to that the TB off. Cut to fit OEM hose.
Expect to replace the "gas" filter on the top front of the intake plenum (the nipple will break if touched)
Clean valve cover (hot tank)
Replace six spark plug tube seals
Replace PCV valve and grommet
Replace spark plugs
Replace spark plug wires if original.
Replace distributor cap and rotor
Replace distributor housing O-ring
Replace air filter
Clean Intake plenum (hot tank), it will be full of carbon
Clean Throttle Body thoroughly with attention to small vacuum ports.
(need new TB gasket)
Clean IAC valve (need new IAC O ring)
Clean timing chain tensioner
Repair/replace Accelerator Cable (can use two foot long sections of dual wall marine grade adhesive lined heat shrink tubing to go over worn/torn rubber covering)
Repair Cruise control and Throttle Cable as needed (heat shrink tubing)
Replace all hose clamps with the correct OEM clamps or Constant Torque type.
Send fuel injectors out to be cleaned (RC engineering, Witch hunter)
Expect some or all of the harness connectors to the fuel injectors to break, you can order new Toyota connectors
Inspect, repair, rewrap main engine harness, add heat sleeve protection. Ensure harness is hung correctly and not drooping on the EGR pipe.
Clean/replace EGR valve (it will be full of carbon). Some people delete the EGR system if no inspections.
Replace radiator and install new radiator cushions
Replace alternator if original (Denso or Toyota)
Replace/rebuild starter (Denso or Toyota)
Replace water pump (Toyota or AISIN)
Replace fan clutch (AISIN)
Replace Alternator belt idler pulley (Toyota or NTK)
Replace AC belt tensioner pulley
Rewrap any harnesses that having peeling tape (TESA tape 51036 is one option)
While radiator and battery are out check for rust, remove, prime, paint areas uncovered
Replace transmission cooler lines
Some people will pull the oil cooler cover, clean, and reseal with new gasket.
Paint air filter box with a 2k paint and primer (SprayMax) The lid, IME, often will develop rust long before the main box
Replace radiator overflow tank
Probably forgot something but all that should keep you busy