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I have used POR15 exhaust and manifold paint a few times. Most recently on my FJ80. I sandblasted the manifold first and then brushed on the POR15. After about 6 months some surface rust started to come back I assumed I did not use enough coats. I had my manifolds off again and this time used 5 coats. Now after a year I still have some surface rust showing up in some spots. Overall they look good,much better than they did before.
EDIT: I went out and looked at my manifolds and there are some "pinholes" of surface rust here and there. Nothing major. I think the POR15 is so thick that it does not like to flow into all of the nooks and crannies of a porous surface like a cast manifold. I remember now that after each coat I would look carefully after they were dry and would see some spots that it looked like I missed, that's why I used 5 coats.