I think ceramics are great in tight spaces and internal stuff, but they are extremely thin coatings and the bennifit is thus reduced. Corrosion resistance is quite good. The stuff peeling off is an aplication problem, not a product problem. I do my own coatings and, when done right, it can last for a very long time. Even on surfaces you dont want it on. Be sure to mask stuff before you spray by the way.
Might also look into the melting point of fiberglass header wrap as I have done it with cheap stuff in the past and it just melts onto the manifold reducing the weave air space bennifit. You can get coated glass wrap good to 1200f and the best I have found is woven cilica wrap also from the same site (inferno wrap), but you can buy it from mopac in langley and other places as well it seems. Thermal transfer so far as I have been able to determine suggest extremely low condictivity sometimes as low as .2 which is almost as low as butter. Although it has a melting point of 1600C I believe, where as butter will melt in your hand. Now I know what your thinking... M&Ms dont melt in your hands, but they do in your mouth and thus are also a poor choice of material. Inferno wrap is quite expensive. 93$ quoted to me for a 1"x 50' roll. Prices on ebay are marginally cheaper.
http://www.heatshieldproducts.com/p...nd-header-heat-wrap/inferno-header-wrap/35/19
product number
325001 1 Inch Wide by 25 Foot Roll
325002 1 Inch Wide by 50 Foot Roll
325005 2 Inches Wide by 15 Foot Roll
325025 2 Inches Wide by 25 Foot Roll
325050 2 Inches Wide by 50 Foot Roll
325100 2 Inches Wide by 100 Foot Roll
325400 4 Inches Wide by 100 Foot Roll