I read a thread on BITOG about fuel and octane a while back; maybe 5 years ago. Basically it was about never running higher than 87 octane unless you need retarded detonation or it can lead to engine damage/failure. It was a few years ago - probably irrelevant to your smell.

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Kind-a thinking what ever set this recent whole thing off popped a flange gasket or one of the joint welds in the exhaust. Going to start crawling around and under/over it tomorrow.