MOST prepackaged stand by systems come plumbed for natty gas, and can be re jetted for LPG. Off the top of my head, the average 10kw unit is going to consume about 1-11/2 gallons of propane an hour at 50% load. This is roughly the output you'll be operating at most of the time. I have not seen any automagical home standbys that operate on gasoline, and unless you've got a couple of banks of batteries(big 6volts in series to make 48-96 vdc), then battery back up is not really a solution. You'd prolly want to use LPG. I have seen 10kws run on 10 gallon LPG bottles.
In order to properly size out your system, I will have you do some research around your place and get some 411 back to me.
First, does your cistern remain full all the time, or is there a chance that power could go out and your cistern be only half full?
I'd imagine you have a sub panel @ your well/cistern. What are the sizes and number of poles on the breakers that feed your:1.pump saver/pump; and 2, your booster pump?
if you have wattage consumption of these devices, I could give you a more accurate guesstimate.
Regarding the baseboards, if they are hydronic, you have to run a pump and the ignitor/ blower on the boiler. Again, i would like breaker sizing or watt consumption. My guess would be somewheres in the neighborhood of 3-6 amps @ 120v for the boiler and pump.
Your fridge and freezer i would assign no less than 1200 watts for each one- or a 15 amp circuit for each.
A ball park guess w/o the info from you in the field would be that you're going to need at least 30 amps @ 240 volts, or a minimum of a 7.2KW generator, IMO.
Being that you want to send power from this genset to the house, garage, and well stand, it would prolly be best to set the unit and its associated $witchgear right next to the main service. Depending on how your distribution is set up will determine exactly what will need to be added/deleted and/or bypassed.
Some pics of your main service, the breakers inside of it, your well stand panels, and you hydronic set up as well as any other sub panels will make laying out your modified distribution easier.