2006 LX - 202k miles: I have been dealing with the exact same issue for the past 4 summers in Las Vegas, since I bought the vehicle. At least 2 - 5 times each summer, when the afternoon temps are nearing or above triple digits and I've been driving it around town and on the freeway (staying on the gas pedal), I will exit the freeway and come to a stop/idle and the engine will misfire and then stall. It doesn't happen every time, but it happens several times every summer, never at a good time or place.
I then have to sit on the side of the road for 10 - 30 minutes, in 100+ degree sun, after which it will start right up as if there was never a problem. I put in a new OEM fuel filter before last summer and that had zero impact on the issue. As soon as the summer hit, it misfired and stalled again. The engine is NOT overheating and it does not throw an error code. However, a couple summers ago, after the misfires/stalls happened several times, the CEL finally did come on along with the VSC TRAC and VSC OFF lights. I was then told by a couple of mechanics that the bank 2 cat was bad and needed to be replaced. I told them that the cat may be an issue NOW, but I didn't believe it was the root of the problem.
Nonetheless, last spring I replaced the bank 2 cat so that I could get the vehicle registered, but I was skeptical the issue had actually been fixed. Sure enough, less than a month later, as soon as the summer arrived, it misfired and stalled in the hot afternoon sun as I tried to accelerate out of a stop. The only time it has ever stalled is in the summer, after I've been driving in the hot afternoon sun, and I come to idle.
Yesterday, it misfired and stalled for the first time this summer, concurrent with the first heat wave of the summer. Oddly, it happened while I was to 50 mph on a highway, but I was going downhill and was not on the gas so the engine was running at low rpms, similar to idling. Unfortunately, this morning, within a few minutes of driving it, the CEL came on along with the VSC TRAC and VSC OFF lights. I haven't checked the code yet, but I'm going to take a wild guess that one of my cats is bad, again, and I'll need to replace it, but it's not going to solve the real issue. I can talk to 10 more mechanics and none of them are going to have a clue what to do other than replace the cat. Yes, I'm frustrated.