Like you said, you can't convert them to CO2. They are designed differently. The difference between CO2 and air tanks is the pressure inside. CO2 will only get about 900lbs (IIRC) of pressure as opposed to the 4500 that the air cylinder will. A puncture on a CO2 tank will not catastrophically explode like an air tank will. For this reason, many people shy away from high pressure air. The other down side is, an air tank will only fill up 3-4 tires depending on tire size. A CO2 tank can fill as many as 12-15 tires.
Like you, I can get surplus cylinders at work, and I can fill them for free. But, the downsides just aren't worth it for me. If you haven't seen the video of the Detroit fire engine that had a cylinder explode (probably 4-5 years ago), you should look for it. The damage was pretty impressive. Luckily, the rig was sitting in the truck bay and no firefighters were in it at the time of the explosion. For $150 or so I can get a CO2 setup from the local Airgas (I got the quote, I just haven't pulled the trigger yet).
Good luck!