There are two races to a bearing. The internal race and an external race. The Loctite product should ONLY be used for the EXTERNAL races.
The external races are only in the hubs, so there is NOT an issue of not getting the hub off the spindle. You should NEVER use this material on the inside of the internal race where it lands on the spindle.
There are two reasons a bearing race spins on one of the front hubs. The first and most common is a loose wheel bearing that causes misalignment and then forces the inner races to seize or bind on the spindle and thus forcing the external race to spin. When the external race spins, it wears out the ID (inside diameter) of the hub, causing the tolerances to open up.
The other reason is that the external races have been removed and replaced so many times that the ID of the hub has been damaged due to the replacement.
I fought loose wheel bearings for years on the front of a Chevy truck until I discovered two things. The first is that I was not adjusting the wheel bearings in the correct procedure. The other is that the hubs I was using had been worked on so many times that they were no longer round. I bought new hubs, installed the external races using a press (not a hammer and punch) then installed the assembly following the FSM procedure. After that, I went 60K+ without having to re-do the wheel bearings. I was thoroughly amazed!
That procedure is the same as the Toyota FSM. Sine the Loctite product has a thicknes to it, you have to make sure that you get the external race properly seated (Square with the interior of the hub) so that when it cures it will be in the correct location. If you have a slight misalignment due to fluid being trapped behind the race, it can cure in a misaligned state and you may get a vibration once it is all assembled. Remember, you are using the product because your tolerances have already opened up and you want to get it close again. It may not be perfect, but it may be acceptable when you are done.
We design and build airlocks and we have to cut bearing seats in cast iron blocks. Sometimes we get the tolerances a bit too much and we can use that same product to lock the new bearing in place. If you replace it, you MUST clean out all the old Loctite material before putting in a new one.
Good Luck!